Lithium acetylides as alkynylating reagents for the enantioselective alkynylation of ketones catalyzed by lithium binaphtholate.
نویسندگان
چکیده
Chiral lithium binaphtholate effectively catalyzed the enantioselective alkynylation of ketones using lithium acetylide as an alkynylating agent. This is the first example of the catalytic enantioselective addition of lithium acetylide to carbonyl compounds without the aid of other metal sources.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 47 19 شماره
صفحات -
تاریخ انتشار 2011